General Chemistry

Cards (26)

  • Spontaneity Process- Type of process which does not need the application of energy to take place.
  • Spontaneity Processes- these process.that occur naturally. it occurs without outside intervention.
  • Process that are spontaneous in one direction are nonspontaneous in the reverse direction.
  • Nonspontaneous Process- Type of process which needs the application of energy to take place. A process which needs the use of energy to make something happen.
  • Entropy- Is a term coined by Rudolp Clausius in the 19th century. A measure of the degree of disorderliness of a system.
  • Entropy- can be thought of as a measure of the randomness of a system. It is related to the various modes of motion in molecules.
  • Gaseous State- Highest
  • Liquid State- Intermediate
  • Solid State- Lowest
  • S Gas> S Liquid- Entropy of Gas compared to Entropy Liquid
  • S Liquid >S Solid- Entropy of Liquid compared to Entropy of Solid
  • Equilibrium- there is a state of balance.
  • State of balance- is also referred to as a state of equilibrium.
  • State of chemical equilibrium- the two opposing process happen at different rates but a certain point in the reaction will be reached where the rates of the forward and backward reactions are the same.
  • Reversible - Reactions in which the products can react to form back the reactants are said to be reversible.
  • In a chemical reaction, chemical equilibrium is the state in which both reactions and products are present in concentrations which have no further tendency to change with time.
  • Forward reaction proceeds at the same rate as the reverse reaction.
  • Reactions rates of the forward and backward reactions are generally not zero, but equal.
  • No net changes in the concentrations of the reactant(s) and product(s).
  • In reversible reactions, the reactants are 
    not completely converted into products and 
    some of the products may be converted 
    back into reactant.
  • For the reaction of the reactants referred to as the 
    forward reaction, aA + bB > cC + dD.
  • For the reaction of the products referred to as the reverse 
    reaction, cC + dD → aA + bB.
  • The rates of the opposing reactions 
    become equal and the system attains 
    equilibrium.
  • Such a state is known as dynamic 
    equilibrium.
  • At equilibrium, the rate of the forward reaction becomes equal to the rate of the reverse reaction.
  • At equilibrium, The forward and reverse reactions continue at equal rates in both directions.