Kinetic Molecular Theory – states that all matter are made up of atoms and molecules constantly moving, they hold kinetic energy and move around in random directions
Particles in ideal gas…
have no volume
don’t attract or repel each other
have elastic collisions
are in constant, random, straight-linemotion
have an average KE directly (∝) related to Kelvin temperature
Particles in a real gas..
have their own volume
attract each other
Note: Real gases can act like ideal gases in ↓ LOWpressures, ↑ HIGHtemperatures, and NONPOLAR atoms and molecules.
Characteristics of Gases
They expand to FILL CONTAINERS. Random motion and no attraction.
They are FLUIDS. Like liquids.
Have VERY LOW density. No volume = lots of empty space.
Can be COMPRESSED.
Undergo DIFFUSION & EFFUSION
Diffusion - spreading of gas molecules
Effusion - passing of molecules through a tiny opening
Note: Diffusion is smelling a perfume scent. Effusion is spraying perfume.
Temperature - K (Kelvin) is the standard
K = °C + 273
°C = (5/9) (F - 32)
Pressure
1 atm (atmosphericpressure) is the standard
101.325 kPa (kilopascal)
1 atm
760 mm Hg
760 torr
The smaller the area, the greater the force.
A barometer is used to measure atmosphericpressure.
Mercury barometer – have liquid
Aneroid Barometer
Mass
The mass of gas in a one-mole sample = molarmass of gas
Ex. If the molar mass of gas X was 40 g/mol, what is its mass? 40g
Volume
A) 1cm3
B) 1dm3
C) 1000l
Boyle's Law (PV = k)
PRESSURE and VOLUME are INVERSE at constant mass & tempP1V1=P2V2
Boyle'sLaw
Examples of Boyle's Law Applications
Breathing – diaphragm move downward (volume of lungs increase), so that air rushes in (pressure inside the lungs lessen)
Syringe
Bicycle pump
Charles’ Law (v/t = k)
VOLUME and TEMPERATURE are DIRECT at constant mass & pressure
V1/T1=V2/T2
EXAMPLES OF CHARLES' LAW:
Balloons in hot and cold temps.
Hot air balloon
Yeast in bread
Gay Lussac’s Law (p/t = k)
PRESSURE and TEMP are DIRECT at constant mass & volume
P1/T1=P2/T2
EXAMPLES OF GAY LUSSAC'S LAW:
Pressure cooker
Firing gun (gunpowder)
Car tires
Charles'Law
Gay Lussac'sLaw
Combined Gas Law
STP (Standard Temperature and Pressure)
Temp - 273 K
Pressure - 1 atm
Combined Gas Law (ᵖᵛ⁄ₜ = k)
PRESSURE and VOLUME are INVERSE, however they are both DIRECT proportional to the TEMPERATURE. At constant temperature
A) P2V2
B) T2
Avogadro’s Principle (ᵛ⁄ₙ = k)
“EQUAL VOLUME = EQUAL NO.MOLES"
VOLUME and N are DIRECT
At constant temperature & pressure
True for ANY gas
A) V2
B) N2
Avogadro'sPrinciple
Ideal Gas Law
Avogadro stated that, "Equal volumes of all gases kept at the same pressure and temperature, contain the same number of molecules." (V/n = k)
The ideal gas equation is useful in illustrating the relationship among the pressure, volume, temperature, and number of moles of a gas.
The universal gas constant (R) is 0.0821L.atmmol.K