sugar polymers containing more than 20 or so monosaccharides
homopolysaccharides
contain only one single type of monomer
heteropolysaccharides
contain two or more different kinds
starch
contain two types of glucose polymer. stored in plants
amylose
unbranched chains of D-glucose residues connected by a1 to 4 linkages
amylopectin
has a high molecular weight up to one million, and highly branched
glycogen
main storage polysaccharide of animal cell.
glycogen
more extensively branched on average 8-12 and more compact than starch
glycogen abundant in liver
dextrans
bacteria and yeast polysaccharides made up of 1a to 6 linked poly-D-glucose
cellulose
fibrous, tough, water insoluable substance is found in the cell wall of the plants
cellulose
constitutes as much as mass of the wood an cotton is almost pure cellulose linked by b1 to 4 glycosidic bonds
chitin
linear homopolysaccharide composed of N-acetyl glucosamine
chitin
principal component of exoskeleton
chitosan
substance produced from the chitin of crustacean shells
chitosan
reduce the fat or cholesterol that the body absorbs from foods
chitosan
helps in blood clotting, and has antimicobacterial property
agar
mixture of sulfated heteropolysaccharides made up of D-galactose and L-galactose derivative ether-linked between C-2 and C-6
heteropolysaccharides
glycosaminoglycan is a family of linear polymers composed of repeating disaccharide
hyaluronic acid (glycosaminoglycan)
contains alternating residues of D-glucuronic acid and N=acetylglucosamine
hyaluronic acid
clear, highly viscous solution that serves as lubricants in synovial fluid of joint and give vitreous humor of the vertebrate
hyaluronate
extracellular matric cartilage and tendons to which contributes tensile strength and elasticity
glycosaminoglycan
has shorter polymers, covalently linked to specific proteins .
chondroitin sulfate (cartilage)
contribute to the tensile strength of cartilage, tendons, ligament, and walls of the aorta
dermatan sulfate (skin)
contribute to the pliability of skin and also present in the blood vessels and hear valves
heparin
variable sulfated with and average of 2.5 sulfate residues per disaccharide iunit. makes it the most highly charged polymer in mammalian
heparin
exclusively in the intercellular granules of the mast cells that occur in the arterial wall
heparin
inhibits the clotting of blood to prevent runaway clot formation
Heparan sulfate
ubiquitous cell surface component as well as an extracellular substance in blood vessel walls and brain . fewer N- and O-sulfate groups and more on N=acetyl groups
Pectin
major component of cell walls, function shock as absorber
heterogenous polysaccharides with a core of a (1 to 4) linked Galacturone residues interested with hexose rhamnose
pectin has a tendency to form high hydrated gels an is exploited in the manufacture of jams and jellies
carbohydrates
on cell surface are some of the best known immunochemical markers
ABO Blood group
they are antigens of oligosaccharide components if glyoproteins