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AS Chemistry
Organic Chemistry
Alcohols
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Cards (18)
What are the 2 methods from making ethanol?
Fermentation
Hydration of ethene
What are the conditions for hydration of ethene?
React with
steam
300
degrees Celsius
6000
kPa
( 60 atm)
Phosphoric
acid
catalyst
What is a biofuel?
fuel
made
from
biological
resources
What are the conditions for the fermentation of glucose to ethanol?
No
oxygen
25-40
degrees Celsius
Compared to hydration, what are the advantages of fermentation of ethanol?
Uses a
renewable
source
Cheaper
equipment
Lower
temperatures
and
pressures
Compared to fermentation what are the advantages of hydration?
Faster
rate of reaction
Continuous
not batch process
Ethanol
produced is
purer
higher percentage economy
Define carbon neutral?
No
overall
carbon dioxide
emission
into
atmosphere
What are the 2 ways in which alcohols can be dehydrated into alkenes?
Reaction with
excess hot concentrated sulfuric acid catalyst
or
Aluminium Oxide catalyst
What can primary alcohols be oxidised into?
aldehydes
What are aldehydes oxidised into?
Carboxylic acids
What are secondary alcohols oxidised into?
ketones
What is the oxidising agent used to oxidise alcohols into aldehydes and ketones?
Acidified potassium dichromate
What colour does the potassium dichromate change from and to?
Orange
to
green
What technique is used when alcohols are being oxidised into ethanoic acid?
reflux
What are the 2 tests used to distinguish between aldehydes and ketones?
Tollens
reagent
Fehling
solution
What is tollens reagent?
solution of
silver nitrate
in
aqueous ammonia
Describe how to carry out the silver mirror test and describe positive result?
Warm
solution with
tollens
reagent
If
aldehydes
present
metallic silver deposits
form
on the inside of test tube
If ketones no change
Describe the Fehlings test and positive result?
Warm
solution with
blue
Fehlings
solution
If
aldehydes
present
a
brick red
precipitate
forms
if ketones present then no change