The colour of iodine solution goes from pale yellow to black if starch is present.
There is less or no black colour if the starch has been mixed with the enzyme amylase, because the starch has been broken down. In other words, the iodine remains a yellow colour.
There is a black colour if the starch is mixed with the enzyme protease. This is because protease doe not break down starch, only protein. The starch causes the iodine to go blue-black.