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PCHEM 2 FINALS
PCHEM 2a
Ether
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Jessa Barrera
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Cards (11)
Ether
Formed by two aryl or
alkyl
groups attached to an
oxygen
atom
Classification of Ether
Symmetrical
: identical alkyl or aryl groups on both sides of O atom
Asymmetrical
: different alkyl or aryl groups on both sides of O atom
Classification of Ether
Aliphatic
: no aryl group is attached to the ether oxygen
Aromatic
: at least one aryl group is attached to the ether oxygen
Ether has a much
lower
boiling point than alcohol and
phenol
due to the absence of an OH group
Even with increased number of
C
atoms, the boiling point of ether is still
low
since there is no OH group
Ether
With the absence of an
OH
group, ethers do not perform
hydrogen
bonding, which means their bonds are mainly non-polar
Ether
Low
polarity
=
less
acidity,
ethers are
less
acidic
than alcohols and
phenols
Ether
With
ether
having non-polar bonds, it has more
stability,
thus having
low
reactivity
Ether
Low
reactivity makes them inert in nature, however, its two lone pairs on the
oxygen
atom helps with a bit of reactivity
Reactions of Ether
Carbon-oxygen
bond is broken when a strong acid reacts with ether, forming an
alkyl halide
and alcohol
Pharmaceutical Importance of Ether
Antiseptic
Solvent
Anaesthetic
Paint
Perfuming
&
flavouring
agent
Recreational
drugs