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Chem Final: Thermodynamics & Hess Law
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Cards (7)
Negative
vs.
positive
enthalpy
-Delta
H =
exothermic:
system → surrounding
+Delta
H =
endothermic:
surrounding → system
Negative vs. positive
entropy
-Delta
S =
orde
r = 1. g → l → s, 2. # of particles
decrease
L → R
+Delta
S =
disorde
r = 1. s → l → g, 2. # of particles
increase
L → R
Negative vs. positive
Gibbs
Free Energy
-Delta
G = thermodynamically
favored
- reaction will
run
as written L → R
+Delta
G = not thermodynamically favored - reaction will
not run
as written L → R
Preferred
states (in thermodynamics)
Exothermic (
-delta H
)
Disorder (
+delta S
)
Thermodynamically favored (
-delta G
)
Delta G
Delta G
=
delta H
-
T(delta S)
Finding Delta
X
sum of x
product
-
sum of x
reaction
Calculating
Calorimetry
q
=
m
*
Cp
*
delta T