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Cards (127)

  • Nanoparticles are useful as catalysts beacause they have a large surface ares so therefore increase the rate of reaction
  • What is the green house effect
    carbon dioxide/greenhouse gases is produced . They absorb heat radiated from earth and reradiate the heat back into the atmosphere
  • why things are in the same homologus series
    same general formula
    trend in physical properties
    same functional group
  • Group 1 elements are the alkali metals
  • Group 1 elements

    • They have one electron in their outer shell
    • As you descend the group, the elements become more reactive
    • The atoms get larger as you descend the group, the outer shell electron is further from the nucleus and more shielded, making it easier to lose the electron
  • Reactivity of Group 1 elements
    • They are extremely reactive and must be stored in oil to prevent reaction with moisture
    • They are soft and can be cut with a knife
    • They oxidize very easily, going from shiny to oxidized quickly on exposure to air
    • They have low melting and boiling points
    • They have low density and float on water
  • Reactions of Group 1 elements
    1. Reaction with oxygen to form oxides
    2. Reaction with cold water to form hydroxides
    3. Reaction with halogens to form salts
    4. Participate in ionic bonding
  • Observations when Group 1 elements are added to water
    • They fizz, releasing hydrogen gas
    • They float and move around
    • They form a small ball that eventually dissolves
    • The resulting solution turns blue with universal indicator, indicating it is alkaline
  • Lithium does not produce a flame when added to water, but sodium produces an orange flame and potassium produces a lilac flame
  • Group 1 metals plus cold water form a metal hydroxide plus hydrogen
  • Group 1 metals below potassium (e.g. francium) will have more violent reactions with water
  • The halogens are the elements in Group 7 of the periodic table
  • States of the halogens at room temperature
    • Fluorine - yellow gas
    • Chlorine - green gas
    • Bromine - red-brown liquid
    • Iodine - grey solid
  • Iodine undergoes sublimation
    It turns directly from a solid to a gas
  • Reactions of halogens with hydrogen
    1. Form hydrogen halides
    2. Hydrogen halides are very acidic and poisonous
    3. Hydrogen halides are very soluble in water
  • More reactive halogens can displace less reactive halogens from their compounds
  • Reactivity of halogens
    • Fluorine is the most reactive
    • Iodine is the least reactive
    • Larger atoms with more electron shells are less reactive
  • Uses of halide salts

    • Sodium chloride - table salt
    • Sodium fluoride - in toothpaste
    • Sodium bromide - disinfectant in swimming pools
    • Sodium iodide - additive in table salt
  • Reaction of halogens with hydrogen
    1. Form hydrogen halides
    2. Hydrogen chloride gas dissolves in water to form hydrochloric acid
  • Test for chlorine gas: it bleaches damp litmus paper
  • Reactivity of halogens
    Can be determined by heating with iron wool - fluorine bursts into flames, chlorine glows brightly, bromine glows dully, iodine just changes color
  • Group 0 elements
    • Also known as the noble gases
    • They are unreactive because they have full outer electron shells
  • Uses of noble gases
    • Krypton - in lighting and photography
    • Argon - in light bulbs and wine barrels
    • Helium - in balloons and airships
    • Neon - in illuminated signs
  • Effect of temperature on reaction rate
    • Increases rate - particles have greater kinetic energy, more frequent and harder collisions
  • Effect of concentration on reaction rate
    • Increases rate - more particles in the same volume, more frequent collisions
  • Effect of surface area on reaction rate
    • Increases rate - more surface area, more frequent collisions
  • Measuring reaction rates
    1. Change in volume over time
    2. Change in concentration over time
    3. Mass change over time (e.g. measuring CO2 production)
    4. Time for a cross to disappear due to precipitate formation
  • Reasons for using catalysts in industrial processes
    To increase profits by making products faster, at lower temperatures, and without the catalyst being consumed
  • Enzymes
    Biological catalysts that speed up reactions without being consumed
  • How enzymes work
    They have an active site where the substrate binds, following the lock and key theory
  • Endothermic and exothermic reactions
    • Endothermic - absorb heat energy, positive ΔH
    • Exothermic - release heat energy, negative ΔH
  • Exothermic reactions heat up the surroundings, endothermic reactions cool them down
  • Active site
    Specific site on enzymes where the substrate binds
  • Lock and key theory
    The way in which the enzyme and substrate fit together
  • Endothermic
    Takes in heat energy
  • Exothermic
    Gives out heat energy
  • Exothermic reaction
    Gets hot
  • Endothermic reaction

    Gets cold
  • Nitric acid is added to potassium hydroxide solution
  • Pipette or burette
    Precise apparatus to measure 25cm cubed of potassium hydroxide solution