Nanoparticles are useful as catalysts beacause they have a large surface ares so therefore increase the rate of reaction
What is the green house effect
carbon dioxide/greenhouse gases is produced . They absorb heat radiated from earth and reradiate the heat back into the atmosphere
why things are in the same homologus series
same general formula
trend in physical properties
same functional group
Group 1 elements are the alkali metals
Group 1 elements
They have one electron in their outer shell
As you descend the group, the elements become more reactive
The atoms get larger as you descend the group, the outer shell electron is further from the nucleus and more shielded, making it easier to lose the electron
Reactivity of Group 1 elements
They are extremely reactive and must be stored in oil to prevent reaction with moisture
They are soft and can be cut with a knife
They oxidize very easily, going from shiny to oxidized quickly on exposure to air
They have low melting and boiling points
They have low density and float on water
Reactions of Group 1 elements
1. Reaction with oxygen to form oxides
2. Reaction with cold water to form hydroxides
3. Reaction with halogens to form salts
4. Participate in ionic bonding
Observations when Group 1 elements are added to water
They fizz, releasing hydrogen gas
They float and move around
They form a small ball that eventually dissolves
The resulting solution turns blue with universal indicator, indicating it is alkaline
Lithium does not produce a flame when added to water, but sodium produces an orange flame and potassium produces a lilac flame
Group 1 metals plus cold water form a metal hydroxide plus hydrogen
Group 1 metals below potassium (e.g. francium) will have more violent reactions with water
The halogens are the elements in Group 7 of the periodic table
States of the halogens at room temperature
Fluorine - yellow gas
Chlorine - green gas
Bromine - red-brown liquid
Iodine - grey solid
Iodine undergoes sublimation
It turns directly from a solid to a gas
Reactions of halogens with hydrogen
1. Form hydrogen halides
2. Hydrogen halides are very acidic and poisonous
3. Hydrogen halides are very soluble in water
More reactive halogens can displace less reactive halogens from their compounds
Reactivity of halogens
Fluorine is the most reactive
Iodine is the least reactive
Larger atoms with more electron shells are less reactive
Uses of halide salts
Sodium chloride - table salt
Sodium fluoride - in toothpaste
Sodium bromide - disinfectant in swimming pools
Sodium iodide - additive in table salt
Reaction of halogens with hydrogen
1. Form hydrogen halides
2. Hydrogen chloride gas dissolves in water to form hydrochloric acid
Test for chlorine gas: it bleaches damp litmus paper
Reactivity of halogens
Can be determined by heating with iron wool - fluorine bursts into flames, chlorine glows brightly, bromine glows dully, iodine just changes color
Group 0 elements
Also known as the noble gases
They are unreactive because they have full outer electron shells
Uses of noble gases
Krypton - in lighting and photography
Argon - in light bulbs and wine barrels
Helium - in balloons and airships
Neon - in illuminated signs
Effect of temperature on reaction rate
Increases rate - particles have greater kinetic energy, more frequent and harder collisions
Effect of concentration on reaction rate
Increases rate - more particles in the same volume, more frequent collisions
Effect of surface area on reaction rate
Increases rate - more surface area, more frequent collisions
Measuring reaction rates
1. Change in volume over time
2. Change in concentration over time
3. Mass change over time (e.g. measuring CO2 production)
4. Time for a cross to disappear due to precipitate formation
Reasons for using catalysts in industrial processes
To increase profits by making products faster, at lower temperatures, and without the catalyst being consumed
Enzymes
Biological catalysts that speed up reactions without being consumed
How enzymes work
They have an active site where the substrate binds, following the lock and key theory
Endothermic and exothermic reactions
Endothermic - absorb heat energy, positive ΔH
Exothermic - release heat energy, negative ΔH
Exothermic reactions heat up the surroundings, endothermic reactions cool them down
Active site
Specific site on enzymes where the substrate binds
Lock and key theory
The way in which the enzyme and substrate fit together
Endothermic
Takes in heat energy
Exothermic
Gives out heat energy
Exothermic reaction
Gets hot
Endothermic reaction
Gets cold
Nitric acid is added to potassium hydroxide solution
Pipette or burette
Precise apparatus to measure 25cm cubed of potassium hydroxide solution