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Chemistry
Chemical Energetics
Bond Energy
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Paul Evangelou
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Bond Energy
: The amount of energy
required
or
released
when a bond is
formed
or
broken
respectively. The unit measure of this energy is
kJ
/
mol.
The
energy change
in a reaction is calculated using the following formula:
Δ
H
=
\Delta H\ =
Δ
H
=
Bond
Breaking
- Bond
Forming
If overall heat energy value is
negative
, reaction is
exothermic
If overall heat energy value is
positive
, reaction is
endothermic
Example of Energy Change
H
2
+
H_2\ +
H
2
+
C
L
2
=
\ CL_2\ =
C
L
2
=
2
H
C
l
\ 2HCl
2
H
Cl
H-H: Bond energy =
436
CL-CL: Bond energy =
243
H - CL: Bond energy =
432
Bond breaking ⟶ 436 + 243 = 679 kj/mol
Bond forming ⟶ 2 (432) = 864 kj/mol
Thus
∆ H
⟶ 676 - 864 = -185 kj/mol
The reaction is
exothermic
in nature