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Module 4
#4.2 Alcohols, Haloalkanes and Analysis
synthetic routes in organic synthesis
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synthetic routes: alkane to haloalkanes
halogen,
UV
light
, free
radical
, substitution
synthetic routes:
alkene
to
alkane
hydrogen (+
Ni catalyst
), 150 degrees,
electrophilic addition
/
hydrogenation
synthetic routes: alkenes to haloalkanes
hydrogen halide
, room temperature,
electrophilic addition
synthetic routes:
haloalkanes
to alcohols
NaOH
, heat under reflux,
nucleophilic substitution
synthetic routes: alcohols to halogenalkane
NaX (+H2SO4) , heat under reflux, nucleophilic substitution
synthetic routes
:
alkene
to alcohols
steam (+
H2SO4
), hydration
synthetic routes: alcohols to
alkene
Al2O3 (
drying
agent) or concentrated acid,heat, elimination/
dehydration
synthetic routes
: alcohols to ketone
K2Cr2O7
/
H2SO4
, heat under
reflux
,
oxidation
synthetic routes: alcohols to aldehyde
K2Cr2O7/H2SO4, distillation, oxidation
synthetic routes
: alcohols to carboxylic acid
K2Cr2O7
/
H2SO4
, heat under
reflux
, oxidation