recrystallisation
dissolve solid in minimal amount of hot solvent
cool solution and filter solid
wash with cool solvent
4.97/122 = 0.0407 mol of benzoic acid
4.85/167 = 0.0290 mol of 3-nitrobenzoic acid
0.0290/0.0407 x100 = 71.3%
melting point test compare to known values to check purity