a substance that only contains one type of element or compound
what does impure mean
it has different substances mixed with it
whats a formulation
a mixture made of definitive proportions according to a formula - it is also made to do something specific
what do impurities do to the melting point
decreases it
what do impurities do tot eh boiling point
increase it
what is the boiling point and melting point like for a pure substance
sharp - eg 27 degrees - 28 degress
whats the boiling point and melting point like for an in pure substance
ranged - eg 27 degrees - 33 degrees - this is because there are multiple different substances in there which each have different melting and boiling points
whats chromatography
technique which separates inks and dyes according to the size of the particle
in chromatography where are the smaller particles compared to the larger particles
smaller particles move further up as the larger particles are heavier
what is the Rf value always between
0-1
how do you calculate Rf value
Rf value = distance travelled by substance (the spot) / distance travelled by solvent
if a substance is more soluble how will it move up the paper
faster
if t a single spot is produced during chromatography what does it mean about the substance being tested
it's pure
if a substance is less soluble, how will it move up the paper
slower
if multiple spots are produced during chromatography, what does it suggest about the substance
its impure
how do you test for hydrogen
you will hear a squeaky pop when a burning splint is held over the open end of a test tube containing hydrogen
how do you test for oxygen
if you put a glowing splint inside a test tube containing oxygen, the oxygen will relight it
how do you test for carbon dioxide
when carbon oxide is bubbled through limewater, the limewater will turn cloudy
how do you test for chlorine
dip damp litmus paper into a test tube of the gas and see if it bleaches and turns white from blue - this shows it is chlorine
if NaOH is added to an unknown solution at it turns into a white precipitate and then more NaOH is added and it turns colourless, what is the unknown
Al3+
if NaOH is added to an unknown solution and it forms a white precipitate and after more NaOH being added it stays white, what is the unknown
either Mg2+ or Ca2+
if NaOH is added to an unknown solution and it turns blue, what is the unknown
Cu2+
if NaOH has been added to an unknown solution and it turns red/brown, what is the unknown
Fe3+
if NaOH has been added to an unknown solution and it tuns green, what is the unknown
Fe2+
what is the paper referred to in chromatography
the stationary phase
what is the term for the line drawn at the bottom of a chromatography paper
base line
what is emission spectroscopy
technique used to analyse the identity and concentration of a substance
how do you test for halides
1) add dilute nitric acid
2) add silver nitrate
3) chloride ion = white precipitate
bromide ion = cream precipitate
iodine ion = yellow precipitate
how do you test for carbonates
1) add HCl to carbonate
2) bubble the gas produced through limewater
3) positive result = limewater goes cloudy as a white precipitate is formed
how do you test for sulfates
1) add dilute HCl
2) add barium chloride solution
3) positive result = white precipitate is formed
what colour flame do lithium compounds produce
crimson red flame
what colour flame do sodium compounds produce
yellow flame
what colour flame do potassium compounds produce
lilac flame
what colour flame do calcium compounds produce
orange / red flame
what colour flame do copper compounds produce
green flame
what are instrumental methods
they are accurate, sensitive and rapid methods which are useful when the amount of sample is very small
describe flame emission spectroscopy
1) spectroscope measures the exact wavelength of the light emitted by a metal ion
2) that allows for definite identification - sometimes colours are difficult to distinguish.
how are concentrations found in flame emission spectroscopy
by measuring the intensity of light emitted. The more intense light, the greater the concentration of the metal ion in a solution.