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Module 3- periodic table and energy
Chapter 9 - enthalpy
Hess' law and enthalpy cycles
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Hess' law states that, if a
reaction
can take place by two routes, and the starting and finishing conditions are the same, the total enthalpy change is the
same
for each route
Hess' law comes from the idea of
conservation
of
energy
using enthalpy changes of
formation
, ∆fH,
∆
r
H
=
∆_rH =
∆
r
H
=
∑
∆
f
H
p
r
o
d
u
c
t
s
−
∑
∆
f
H
r
e
a
c
t
a
n
t
s
∑∆_fH products - ∑∆_fH reactants
∑
∆
f
H
p
ro
d
u
c
t
s
−
∑
∆
f
Hre
a
c
t
an
t
s
using
enthalpy
changes of
combustion
, ∆cH,
∆
r
H
=
∆_rH =
∆
r
H
=
∑
∆
c
H
r
e
a
c
t
a
n
t
s
−
∑
∆
c
H
p
r
o
d
u
c
t
s
∑∆_cH reactants - ∑∆_cH products
∑
∆
c
Hre
a
c
t
an
t
s
−
∑
∆
c
H
p
ro
d
u
c
t
s