Electrically charged particle, formed when an atom or molecule gains or loses electrons
Atom
The smallest part of an element that can exist
Charge
Property of matter that causes a force when near another charge. Charge comes in two forms, positive and negative.
Electron
Subatomic particle, with a negative charge and a negligible mass relative to protons and neutrons
Metal
Shiny element that is a good conductor of electricity and heat, and which forms basic oxides
Non-metal
Element that is a poor conductor of electricity and heat, and which forms acidic oxides
Forming positive ions
1. Metal atoms lose electrons from their outer shell
2. The ions formed have full outer shells
3. The ions have the electronic structure of a noble gas (group 0 element), with a full outer shell
Forming negative ions
1. The outer shells of non-metal atoms gain electrons
2. The ions formed are negative, because they have more electrons than protons
3. The ions have the electronic structure of a noble gas (group 0 element), with a full outer shell
For elements in groups 1, 2 and 3, the number of electrons lost is the same as the group number
For elements in groups 6 and 7, the charge on the ion is equal to (8 minus group number)
Ions
Formed by the transfer of electrons
Ion charges and groups
Group 1 Element Na Ion charge + Ion symbol Na +
Group 2 Element Mg Ion charge 2+ Ion symbol Mg 2+
Group 6 Element O Ion charge 2- Ion symbol O 2-
Group 7 Element Cl Ion charge - Ion symbol Cl -
Ionic compound
A giant lattice structure made up of charged particles called ions, with strong electrostatic forces of attraction
Ionic lattice
Regular, repeating arrangement of ions
Oppositely charged ions next to each other
A single grain of salt may contain 1.2 × 10^18 (1,200,000,000,000,000,000) ions
The lattice arrangement continues in three dimensions, which is why solid ionic compounds form crystals with regular shapes
Ionic bonding
Strong electrostatic forces of attraction between the oppositely charged ions, acting in all directions in the lattice
Different types of models are used to represent giant ionic structures, each with advantages and limitations
The two-dimensional space-filling model clearly shows the arrangement of ions in one layer, but does not show how the next layer is arranged
The three-dimensional ball and stick model shows the arrangement of ions in a larger section of the crystal, but using sticks for bonds is misleading because the forces of attraction actually act in all directions
The three-dimensional model is also misleading because it shows lots of free space between the ions, which there isn't
Ionic compound
Made up of charged particles, called ions. Has a giant lattice structure with strong electrostatic forces of attraction.
Ionic compounds
Have regular structures, called giant ionic lattices
Have strong electrostatic forces of attraction acting in all directions between the oppositely charged ions
Ionic lattice
The regular arrangement of ions in an ionic substance
Properties of ionic compounds
High melting and boiling points
Can conduct electricity when melted or in solution
Cannot conduct electricity in the solid state
Ionic compounds have high melting and boiling points
Because energy must be transferred to overcome the strong electrostatic forces of attraction between the oppositely charged ions
Ionic compounds can conduct electricity when melted or in solution
Because the ions are then free to move from place to place
Ionic compounds cannot conduct electricity in the solid state
Because the ions are held in fixed positions and cannot move
The strength of the ionic bonds depends on the charge on the ions. Ions with higher charge will have stronger forces between them, so will need more energy to overcome these forces.
Covalent bond
A shared pair of electrons
Covalent bonding
Forms molecules
Substances with small molecules
Have low melting and boiling points
Do not conduct electricity
A covalent bond is a shared pair of electrons
Covalent bonding forms molecules
Substances with small molecules have low melting and boiling points, and do not conduct electricity
Melting point
The temperature at which a solid changes into a liquid as it is heated
Boiling point
The temperature at which a substance rapidly changes from a liquid to a gas
When a simple molecular substance melts or boils
It is the intermolecular forces that are broken, not the covalent bonds in each molecule
Intermolecular forces
Weak attractive forces between molecules
Intermolecular forces are much weaker than the strong covalent bonds in molecules