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Cards (47)
What is the main topic of the A-level chemistry explanation video discussed?
Periodicity
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What are the four properties that will be explored in relation to periodicity?
Atomic radius, electronegativity,
ionization
energy, melting and
boiling
points
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What does periodicity refer to in chemistry?
It is the study of the
repeating patterns
or
trends
in physical or chemical properties in the periodic table.
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What are the two main ways to categorize elements in the periodic table?
Groups
(
columns
) and periods (rows)
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What does the block of an element in the periodic table correspond to?
The
subshell
that contains the
outer electrons
of the element.
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What are the s block elements characterized by?
They have their
outer electrons
in the s subshell.
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What are the p block elements characterized by?
They have their
outer electrons
in the
p
subshell.
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What are the d block elements also known as?
Transition
elements
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How does the position of elements in the periodic table affect their properties?
The position affects
properties
such as atomic radius,
electronegativity
, ionization energy, and melting and boiling points.
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What is atomic radius?
It is the distance between the
nucleus
and the
outermost
electrons of an atom.
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What happens to atomic radius as you move across period three?
The atomic radius
decreases.
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Why does atomic radius decrease across period three?
Because the
nuclear charge
increases, pulling the
outer electrons
closer to the nucleus.
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What is
electronegativity
?
It is the ability of an atom to
attract electron density
in a
covalent
bond.
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How does electronegativity change across period three?
Electronegativity
increases.
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What is the relationship between atomic radius and electronegativity?
A
smaller
atomic radius leads to
higher
electronegativity due to increased attraction to the nucleus.
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What is
ionization energy
?
It is the energy required to remove a
mole
of electrons from a
mole
of gaseous atoms.
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How does ionization energy change across period three?
Ionization energy
increases.
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Why does ionization energy increase across period three?
Because the
nuclear charge
increases and the
outer
electrons are closer to the nucleus.
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What are the patterns of ionization energy across period three?
General increase in ionization energy from
sodium
to
argon
Two dips
in the pattern:
Between
magnesium
and aluminium (due to removal from a
p
subshell)
Between
phosphorus
and
sulfur
(due to electron repulsion in the p subshell)
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What is the significance of the dips in the ionization energy graph across period three?
The dips indicate changes in subshells and
electron repulsion
affecting the
energy
required to remove electrons.
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What is the most electronegative element in the periodic table?
Fluorine
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Where are the most electronegative elements found in the periodic table?
In the
top right corner.
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Where are the least electronegative elements found in the periodic table?
In the
bottom left
corner.
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What are the patterns of electronegativity within a
group
?
Electronegativity
increases
as you go up a group
Atoms get
smaller
, bringing the nucleus
closer
to bonding electrons
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What are the key points to remember about the periodicity topic for exams?
Understand the definitions of
atomic
radius,
electronegativity
, and ionization energy
Know the
patterns
across periods and within
groups
Be able to explain the
reasons
behind these patterns
Be prepared to sketch
graphs
showing these trends
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How many orbitals are in a p sub shell?
Three
orbitals
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How do the electrons in the p sub shell of phosphorus occupy the orbitals?
Each
electron
occupies the
orbitals singly
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What happens to the electrons in the p sub shell of sulfur compared to phosphorus?
One of the orbitals has
two
electrons in sulfur
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Why does one of the electrons in sulfur have slightly more energy than expected?
Due to the
repulsion
between the two
negatively
charged electrons
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What is the general trend in ionization energy across a period?
It generally
increases
with some
dips
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What is the pattern of ionization energy as you move down a group?
It decreases because
electrons
are further from the
nucleus
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What are the three states of matter and their characteristics?
Solids
: Regular layers, particles vibrate in fixed positions, strong forces between particles.
Liquids
: Close particles, more random arrangement, particles move around more due to higher energy.
Gases
: Lots of space between particles, high energy, particles move rapidly, weak forces between particles.
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What is the
melting point
?
The
temperature
at which a solid turns into a
liquid
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What influences the melting point of a substance?
The
strength
of the forces between the
particles
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How does the boiling point relate to the melting point?
Boiling points are always
higher
than melting points
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What is the pattern of melting points across period three?
There are
three
distinct regions based on
bonding
types
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What type of bonding do sodium, magnesium, and aluminum exhibit?
Metallic
bonding
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Why does aluminum have a higher melting point than sodium?
Aluminum has a greater
charge density
and stronger
metallic
bonding
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What type of structure does silicon have?
Silicon has a giant
covalent
structure
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What is the melting point of silicon compared to the metals in period three?
Silicon has the
highest
melting point of any
element
in the period
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