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Lattice enthalpy and entropy
Chem *
29 cards
Important definitions Mod 2
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27 cards
4.1.1: Basics of Org Chem
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More chem card?
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Cards (246)
Who is the presenter of the video on organic synthesis and analytical techniques?
Chris Harris
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What is the purpose of the video on organic synthesis and analytical techniques?
It is designed for
revision
.
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What analytical techniques are mentioned in the video?
Infrared spectroscopy
and
mass spectrometry
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What do greenhouse gases do with infrared radiation?
They
absorb
and
reemit
it towards Earth.
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Which greenhouse gases are mentioned in the video?
Carbon dioxide
,
water vapor
, and
methane
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What human activities increase greenhouse gases?
Burning
fossil fuels
and using
landfills
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What is the greenhouse effect?
It is the warming of Earth due to
gases
.
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What correlation is observed between carbon dioxide levels and temperature?
As
CO2
levels increase, temperature fluctuates.
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What does correlation not imply according to the video?
Correlation does not imply
causation
.
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What international agreement was made in 1997 regarding CO2 emissions?
The
Kyoto Protocol
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What did the Kyoto Protocol aim to address?
It aimed to limit
CO2
emissions globally.
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What actions has the UK government taken to reduce emissions?
Increased use of
renewable energy sources
.
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What is infrared spectroscopy used for?
To analyze
vibrational energy
of bonds.
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How does infrared radiation affect molecular bonds?
It increases the
vibrational energy
of bonds.
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What does the broad peak at about 3000 cm<sup>-1</sup> indicate in infrared spectroscopy?
It indicates the presence of an
O group
.
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What happens to the O peak when an alcohol is oxidized?
The O peak disappears in the spectrum.
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What is the purpose of breathalyzers?
To monitor
alcohol
levels in breath.
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How do breathalyzers measure alcohol levels?
By measuring the intensity of the
CH peak
.
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What does mass spectrometry determine?
The
relative molecular mass
of a compound.
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What does the M/Z ratio represent in mass spectrometry?
Mass of a
fragment
divided by its
charge
.
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What happens to molecules in a mass spectrometer?
They are bombarded and fragmented by
electrons
.
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What is the molecular ion peak in mass spectrometry?
It represents the
unfragmented
molecule's mass.
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How can fragmentation patterns help identify molecules?
Different
fragments
indicate different molecules.
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What is a common fragment mass for a methyl group?
15
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What is a common fragment mass for a carbonyl group?
28
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What are the key features of infrared spectroscopy?
Uses infrared radiation to analyze molecular
bonds
Measures
vibrational energy
of bonds
Peaks indicate presence of specific
functional groups
Broad peaks suggest certain types of bonds
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What are the applications of mass spectrometry?
Determines
relative molecular mass
Identifies
molecular fragments
Analyzes complex mixtures
Monitors emissions and pollutants
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What are the implications of global warming?
Increased
greenhouse gas emissions
Rising global
temperatures
Impact on climate and weather patterns
Need for international agreements to reduce emissions
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What are the differences between infrared spectroscopy and mass spectrometry?
Infrared spectroscopy analyzes
vibrational energy
Mass spectrometry analyzes
mass-to-charge ratio
Infrared identifies functional groups
Mass spectrometry identifies
molecular fragments
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What are the main sources of greenhouse gases?
Burning
fossil fuels
Landfills releasing
methane
Deforestation
Industrial processes
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What are the effects of human activities on global warming?
Increased
CO2
emissions
Enhanced
greenhouse effect
Climate change
Ocean acidification
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What can fragmentation patterns be used for?
To identify molecules with the same
constituent
atoms
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Why are fragment masses different for molecules with the same formula?
Because they
break
at different points
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What is the molecular formula for propanal and propanone?
Both have the same
molecular formula
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How can fragmentation help distinguish between propanal and propanone?
By analyzing their
unique
fragmentation patterns
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What is the molecular ion mass for propanal?
58
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What are the major fragments for propanal?
CH<sub>3</sub>CH<sub>2</sub>
(
29
) and
CO
(29)
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What is a major fragment for propanone?
CH<sub>3</sub>CO<sup>+</sup>
(
43
)
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How does the intensity of peaks differ between propanal and propanone?
Propanone
has a
greater
intensity
of
peaks
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How can spectra be used to identify molecules?
By comparing against a
library
of spectra
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