ir spec

Cards (15)

  • What is the name of the analytical technique that uses infrared radiation to identify compounds?
    Infrared spectroscopy
  • How does infrared spectroscopy help in identifying compounds?
    It uses infrared radiation that is absorbed by molecular bonds, causing them to vibrate.
  • What happens to the bonds in molecules when infrared radiation is fired at them?
    The bonds absorb the radiation and start to vibrate, stretching and bending in different ways.
  • What factors influence how quickly a bond oscillates or vibrates in infrared spectroscopy?
    The atoms or groups attached to either side of the bond influence its oscillation speed.
  • What is the significance of the fingerprint region in infrared spectroscopy?
    • It is below 1,500 cm<sup>-1</sup> and is generally messy.
    • Unique to each individual molecule.
    • Can be compared to known spectra for identification.
  • How is frequency measured in infrared spectroscopy?
    Frequency is measured in wave numbers, which are expressed in cm<sup>-1</sup>.
  • What does a broad peak at around 3,200 cm<sup>-1</sup> indicate in an infrared spectrum?
    It indicates the presence of an alcohol group.
  • How can the shape of a peak in infrared spectroscopy help identify functional groups?
    A broad peak suggests an alcohol, while a sharp peak suggests an amine (NH).
  • What does a peak at about 2,900 cm<sup>-1</sup> typically signify?
    It signifies the presence of a CH group in organic compounds.
  • What does a peak around 1,700 cm<sup>-1</sup> indicate in an infrared spectrum?
    It indicates the presence of a carbonyl (C=O) group.
  • What can a peak at about 1,300 cm<sup>-1</sup> signify in infrared spectroscopy?

    It can signify the presence of a CO bond, possibly indicating an ether or ester.
  • What are the limitations of using infrared spectroscopy in isolation?
    • Cannot be used alone for definitive identification.
    • Often used in conjunction with other techniques like gas chromatography and NMR.
    • Provides partial information that needs to be pieced together.
  • What is the role of known spectra in infrared spectroscopy?

    Known spectra are used to compare and identify unknown molecules.
  • Why is infrared spectroscopy considered powerful in identifying unknown substances?

    Because it can provide information about the types of bonds present in a molecule.
  • How do different types of spectroscopy and spectrometry work together in analysis?
    They provide complementary information that helps to identify unknown substances effectively.