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saleh harhara
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Cards (15)
What is the name of the analytical technique that uses infrared radiation to identify compounds?
Infrared spectroscopy
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How does infrared spectroscopy help in identifying compounds?
It uses
infrared radiation
that is absorbed by
molecular
bonds, causing them to vibrate.
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What happens to the bonds in molecules when infrared radiation is fired at them?
The bonds
absorb
the radiation and start to
vibrate
,
stretching
and
bending
in different ways.
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What factors influence how quickly a bond oscillates or vibrates in infrared spectroscopy?
The atoms or groups attached to either side of the bond influence its oscillation speed.
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What is the significance of the fingerprint region in infrared spectroscopy?
It is below
1,500
cm<sup>-1</sup> and is generally messy.
Unique
to each individual molecule.
Can be compared to known
spectra
for
identification.
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How is frequency measured in infrared spectroscopy?
Frequency is measured in wave numbers, which are expressed in cm<sup>-1</sup>.
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What does a broad peak at around 3,200 cm<sup>-1</sup> indicate in an infrared spectrum?
It indicates the presence of an
alcohol
group.
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How can the shape of a peak in infrared spectroscopy help identify functional groups?
A broad peak suggests an
alcohol
, while a sharp peak suggests an
amine
(NH).
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What does a peak at about 2,900 cm<sup>-1</sup> typically signify?
It signifies the presence of a
CH
group in
organic
compounds.
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What does a peak around 1,700 cm<sup>-1</sup> indicate in an infrared spectrum?
It indicates the presence of a carbonyl (C=O) group.
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What can a peak at about 1,300 cm<sup>-1</sup> signify in infrared
spectroscopy
?
It can signify the presence of a
CO bond
, possibly indicating an
ether
or ester.
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What are the limitations of using infrared spectroscopy in isolation?
Cannot be used alone for definitive identification.
Often used in conjunction with other techniques like gas chromatography and NMR.
Provides partial information that needs to be pieced together.
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What is the role of known spectra in infrared
spectroscopy
?
Known spectra
are used to compare and identify
unknown molecules.
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Why is
infrared spectroscopy
considered powerful in identifying unknown
substances
?
Because it can provide information about the types of
bonds
present in a
molecule.
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How do different types of spectroscopy and spectrometry work together in analysis?
They provide complementary information that helps to identify unknown substances effectively.
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