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A level chemistry
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Cards (154)
What is optical isomerism a form of?
Stereoisomerism
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What do optical isomers have in common?
They have the same
structural formula
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How do optical isomers differ from each other?
They have different
arrangements
of atoms in space
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What is a chiral carbon atom?
A carbon atom with
four
different
groups
attached
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What is a classic example of a chiral center?
Human
hands
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What are enantiomers?
Optical isomers
that are mirror images of each other
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What does non-superimposable mean in the context of optical isomers?
They cannot be placed on top of each other to match perfectly
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How can you visually demonstrate that two hands are non-superimposable?
By trying to overlap them
without
complete matching
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What is the first step in identifying a chiral center in a molecule?
Find the
carbon atom
with
four different groups
surrounding it
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What is the tetrahedral shape associated with in chemistry?
The arrangement of groups around a
chiral carbon
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How do you represent enantiomers in a diagram?
By drawing a
mirror line
between them
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What is plane polarized light?
Light that
oscillates
in only one direction
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How do optically active isomers affect plane polarized light?
They
rotate
the
plane
of
polarized
light
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What is the relationship between the rotation of plane polarized light and enantiomers?
One enantiomer rotates it
clockwise
, the other
counterclockwise
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What type of amino acids are mostly found in nature?
L
amino acids
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What is ascorbic acid commonly known as?
Vitamin C
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What functional group do aldehydes and ketones contain?
A
carbonyl
functional group
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Where is the carbonyl group located in aldehydes?
At the
end carbon
of the molecule
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How do you name an aldehyde?
By ending the name with "
al
"
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How do you name a ketone?
By ending the name with "one"
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What is the difference in the position of the carbonyl group between aldehydes and ketones?
Aldehydes have it at the
end
, ketones have it in the
middle
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What functional group do aldehydes and ketones contain?
Carbonyl
functional group
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What is the main difference between aldehydes and ketones?
The position of the
carbonyl group
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What is the name of the aldehyde with three carbon atoms?
Propanal
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What is the name of the ketone with three carbon atoms?
Propanone
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How do you specify the position of the carbonyl group in longer carbon chains for ketones?
By numbering the carbon chain and indicating the
carbon number
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What is the functional group present in phenols?
Hydroxyl group
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What is a benzene ring composed of?
Six
carbon atoms
with a
delocalized electron system
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What is the name of the compound formed when a methyl group is added to phenol?
Two methylphenol
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What is salicylic acid used for?
To make
aspirin
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What defines a diol?
A molecule with two
hydroxyl
groups
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How are diols named?
By counting the
carbons
and assigning numbers to the
hydroxyl groups
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What is the name of the diol with two hydroxyl groups on the same carbon?
Ethan-1,1-diol
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What is the name of the diol with hydroxyl groups on the first and second carbons?
Ethan-1,2-diol
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What is the name of the diol with hydroxyl groups on the second and third carbons?
Butane-2,3-diol
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What are acid anhydrides made from?
Two
carboxylic acids
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What is the general formula for acid anhydrides?
RCO2CO
R
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How are acid anhydrides named?
By removing "acid" from the
carboxylic acid
name and adding "anhydride"
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What is the name of the acid anhydride made from ethanoic and propanoic acids?
Ethanoic propanoic anhydride
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How do you name an acid anhydride made from the same carboxylic acid?
By naming it once
followed
by
"anhydride"
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