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chemistry paper 2
organic chemistry
alcohols + carboxylic acids + esters
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Benjamin
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Cards (65)
What are alcohols classified as in organic chemistry?
Homologous series
of organic compounds
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How do alcohols differ from alkanes?
Alcohols have an
-OH
group instead of hydrogen
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What is the naming convention for alcohols?
Replace
the final 'e' with 'ol'
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What are the first four alcohols in the homologous series?
Methanol
, ethanol,
propanol
, butanol
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What is the general formula for alcohols?
C
n
n
n
H
2
n
+
2n +
2
n
+
1
1
1
OH
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What does it mean for alcohols to be soluble?
They can dissolve in
water
to form a solution
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What is the pH of alcohol solutions?
Neutral
pH
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What happens when alcohols are oxidized?
They form
carboxylic acids
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How do you write the combustion equation for ethanol?
C
2
2
2
H
5
5
5
OH + O
2
2
2
→ CO
2
2
2
+ H
2
2
2
O
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What does flammability mean for alcohols?
They can undergo
complete combustion
in air
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Why are alcohols used as fuels?
They release a lot of
energy
when burned
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What is one common use of alcohols in industry?
As
solvents
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Why are alcohols preferred over water as solvents?
They can
dissolve
substances
that
water cannot
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What are the properties of the first four alcohols?
Flammable
Soluble
in water
Can be oxidized to form
carboxylic acids
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What is the process of combustion for alcohols?
Alcohol reacts with oxygen
Produces
carbon dioxide
and water
Releases
energy
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What is the functional group of carboxylic acids formed from alcohols?
The functional group is
-COOH
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What are carboxylic acids a homologous series of?
Organic compounds
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What is the functional group of carboxylic acids?
c-o-o-h
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What do the names of carboxylic acids end with?
anoic acid
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What is the name of the carboxylic acid with three carbons?
Propanoic acid
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What are the other carboxylic acids you need to know?
Methanoic
, ethanoic,
butanoic
acids
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How should the formulas of carboxylic acids be written?
COOH
groups together at the end
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How do carboxylic acids behave in reactions?
They react like
any
other
acid
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What type of acids are carboxylic acids?
Weak acids
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What does it mean that carboxylic acids do not fully ionize?
Not all molecules release
hydrogen ions
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How is the ionization of carboxylic acids represented?
With an
equilibrium arrow
in equations
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What do the negative ions formed from carboxylic acids end with?
anoate
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What does propanoic acid ionize into?
Propanoate
ion and hydrogen ion
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What do carboxylic acids form when they react with metal carbonates?
Salt, water, and
carbon dioxide
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What is formed when ethanoic acid reacts with potassium carbonate?
Potassium ethanoate
, water, and
carbon dioxide
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How are carboxylic acids made from alcohols?
By
oxidizing
alcohols with an
oxidizing agent
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What is the name of the carboxylic acid produced from butanol?
Butanoic acid
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What happens to butanol during oxidation?
It adds an oxygen to form a
carboxylic acid
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What are the key characteristics of carboxylic acids?
Homologous series
of organic compounds
Functional group: c-o-o-h
Names end in "
anoic acid
"
Weak acids
that do not fully ionize
Form negative ions ending in "
anoate
"
React with
metal carbonates
to produce salt, water, and carbon dioxide
Made by oxidizing
alcohols
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What is the key feature of esters?
They have a
COO
group
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What is the functional group of esters called?
COO
group
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How are the smells of esters typically described?
As
sweet
or
fruity
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What does it mean for esters to be volatile?
They
evaporate
easily
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In what products are esters commonly found?
Perfumes
and food
flavorings
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What two substances are needed to make an ester?
A
carboxylic acid
and an
alcohol
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