Bonding

Subdecks (2)

Cards (38)

  • Effective nuclear charge is the electrostatic attraction valence electrons experience towards the nucleus.
  • Ionization energy is the amount of energy required to remove an electron from a gaseous atom.
  • Electron affinity is the change in energy of a gaseous atom when an electron is added to the atom, forming an anion.
  • Effective nuclear charge = Total number of protons - Total number of shielding electrons
  • Covalent bonding is the electrostatic attraction between a shared pair of electrons and a positively charged nuclei.
  • Ionic bonding is the electrostatic attraction between a lattice of cations and anions
  • Metallic bonding is the electrostatic attraction between a lattice of cations and a sea of delocalized electrons
  • London dispersion force occurs when there is a temporary electrostatic attraction between molecules due to an instantaneous dipole.
  • Dipole-dipole forces occurs when there is an electrostatic attraction between polar molecules and their permanent dipoles.
  • Hydrogen bonding (intermolecular force) occurs when a hydrogen is bonded to oxygen, nitrogen, or fluorine due to their extreme electronegativity.
  • Intramolecular force describes the forces within a molecule while intermolecular force describes the forces between molecules.
  • Relationship between intramolecular and intermolecular
  • Strength of Intermolecular forces from least to greatest
    London dispersion < Dipole-dipole < Hydrogen bonding
  • Bond polarity & differences in electronegativity
  • Bond polarity diagrams
  • A molecule may have polar bonds present but the symmetry of the molecule may prevent the molecule as a whole being polar if the dipole moments of the individual bonds cancel out.
  • Polar molecules will dissolve in polar solvents, such as water.
  • Non-polar molecules will dissolve in non-polar solvents, such as hexane.