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Stage 3 Dental Materials Science
Casting
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Eleanor Jubb
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Factors that influence casting:
Selection
of the correct
type
of
investment
The
type
of
casting machine
/
equipment
The
design
of
mould
Investment composed of:
Refractory material -
silica
Binder -
gypsum
or
phosphate
Mix investment with
water-based
liquid - pour around wax-pattern and allow to set
For accurate casting:
total
shrinkage by
alloy
=
total
expansion by
mould
Compensation for casting shrinkage:
Gold
alloys ~1.5%
Base
alloys ~ 2-2.5%
Expansion for mould in investment comes from:
Setting of
investment
(
crystal growth
)
Hygroscopic expansion
caused by adding
water
to investment during setting
Expansion when
heating
the
mould
to casting
temperature
Inversion of
silica
(
quartz
or
cristobalite
)
For
phosphate-bonded investments
: ratio of
water
to "
special liquid
"
Important: different manufacturers require different
procedures
to get
expansion
Selection of the correct type of investment:
Needs
to
compensate shrinkage
: possible error - casting too big or too small
Needs thermal stability
: possible error - sulphide deposits (gypsum investment breakdown)
Must heat investment slowly
:
Investments
are
insulators
,
cracks
can form during
heating
Possible casting errors
- fins
Investment
must not have
large pores
at the
mould surface
Need
to
use
a
mixture
of
investment particle size
Possible
casting
error -
bubbling
on
casting surface
Casting metals and alloys:
Metal/alloy must be
fully
molten
when poured into mould
Must heat to above the
liquidus
line
The
higher
the temperature the greater the chance of
air
incorporation
This could lead to
porosity
in the
casting
NOTE:
base
metal
alloys
have
higher
melting temperatures than
gold
alloys
Casting metals and
alloys
:
The
metal
/alloy must
flow
into all of the
mould
BUT
liquid
metals/
alloys
have
high
surface
tensions
Gravity
will not be enough to force the metal/alloy into the whole
mould
- this would lead to "
short
" castings
The
metal
/alloy must displace the
air
in the mould
Need
air
to
escape
The
investment
material will have some
pores
Mould
base thickness affects amount of
air
that can escape
If
air
doesn't fully escape
Some
gas
will
bubble
back - causing
porosity
in the casting
Casting machines:
Machines needed to force the
molten alloy
into the
mould
Centrifugal force
commonly used
Traditionally casting was performed by
hand
Suitable for small castings made from
gold alloys
High density
provided
high force
-
thrust
Base alloys
have
low density
-
insufficient force
Modern casting machines
Electric motor
allows
higher speeds
Method of melting the alloys:
Gas
/
air flame
Provides enough
heat
for
gold alloys
Too
low
for
base metal alloys
Oxy
/
acetylene
flame
Higher temp
possible - suitable for
base metal alloys
Ratio
of
oxygen
:
acetylene
must be carefully
controlled
Too much O₂ leads to
oxidation
of the
casting
Too much
acetylene
leads to
carbide embrittlement
of the
casting
Induction
heating
Better control of the
heating rate
and
temperature
possible
Most commonly used currently
Design
of the
mould
-
investment base thickness
(x)
Must be
thick
enough to provide
stable mould
Too
thick
can lead to
poor air flow
-
air
cannot escape the
mould properly
Potential problems:
rounded edges
and
loss
of detail
Solution:
thin base
and for
phosphate
bonded investments add a
vent
Design of the mould -
sprue
required to allow
alloy
to enter the
mould
:
Allows the
flow
of the
material
to be
controlled
Must
be
removed
after
casting
- trimmed by
technician
Design
of the
mould
- for successful casting:
The material at the
extremity
of the casting should solidify
first
The material in the sprue should solidify
last
If material in sprue solidifies too
early
insufficient alloy will enter the mould
Potential problem: casting
porosity
Complicated castings:
For
larger
castings (multi-unit devices, bridges, etc.)
Moulds
are more
complex
Harder for
alloy
to
penetrate mould extremities
whilst
molten
The chance of
solidifying
in the
sprue increases
Multiple
sprues
Molten alloy enters
mould
in
multiple locations
Easier
for
alloy
to
penetrate extremities
Requires more
post-processing
(
polishing
)
Sprue reservoir
Thinner sections
cool faster
than
thicker
sections
Reservoir
thicker
than
sprue
and
casting
Solidifies
last
Casting errors:
Problem = too small
Likely cause =
too little mould expansion
How to avoid fault =
use correct temperature and investment materials
Casting errors:
Problem = too large
Likely cause = too much
mould expansion
How to avoid fault = use
correct temperature
and
investment materials
Casting errors:
Problem = distorted
Likely cause =
stress relief
of wax pattern
How to avoid fault =
warm wax thoroughly
before creating
pattern
Casting errors:
Problem = rough surface
Likely cause = breakdown of
investment
,
air bubbles
on
wax pattern
,
weak investment
How to avoid fault =
Do not
overheat mould
or
alloy.
Use correct investment.
Use
wetting agent
and/or
vacuum-investing technique.
Avoid using too much
water
when
mixing investment.
Casting errors:
Problem = fins
Likely cause = cracking of
investment
How to avoid fault = avoid
heating investment
too
rapidly
Casting errors:
Problem = irregular voids
Likely cause = casting
shrinkage
of
alloy
,
turbulent flow
of
molten alloy
,
inclusion
of
particles
of
investment
How to avoid fault =
Place
sprues
of correct
diameter
and
reservoir
at (or near) the
bulkiest
section of the pattern
Heat mould
upside down so that any
loose particles
fall out
Casting errors:
Problem =
spherical voids
Likely cause =
gases dissolve
in
molten alloy
and form
bubbles
when it
cools
How to avoid fault = do not
overheat alloy
for
too long
Casting errors:
Problem = oxidation of surface
Likely cause =
overheating
in
air
How to avoid fault =
Do not use an
oxidising flame
or
heat
for too long
Use a
flux
to protect
molten alloy
Casting errors:
Problem = sulphide deposits
Likely cause = breakdown of
investment
(particularly
gypsum-bonded
)
How to avoid fault =
Do not
overheat
the investment
Use correct
investment
Casting errors:
Problem = rounded margins
Likely cause =
back-pressure
of
air
due to
low porosity
of
mould
How to avoid fault =
Place pattern near end of the casting ring. Use
porous investments
(or
vents
)
Ensure there is
no wax
left and cast with
sufficient force
Casting errors:
Problem = short castings
Likely cause =
alloy deficiency
;
mould
too
thin
, too
cold
, or had
blocked sprues
;
insufficient casting force
How to avoid fault =
Use enough
alloy
; make sure completely
molten
Use correct
diameter sprues
and
heat
to correct
temperature
Ensure
casting machine
applies sufficient
force
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