Make estimates of the results of simple calculations
MS 4a
Translate information between graphical and numeric form
MS 4b
Drawing and interpreting appropriate graphs from data to determine rate of reaction
MS 4c
Plot two variables from experimental or other data
MS 4d
Determine the slope and intercept of a linear graph
MS 4e
Draw and use the slope of a tangent to a curve as a measure of rate of change
Factors which affect the rates of chemical reactions include: the concentrations of reactants in solution, the pressure of reacting gases, the surface area of solid reactants, the temperature and the presence of catalysts
Students should be able to
Recall how changing these factors affect the rate of chemical reactions
pH
Measure of rate of reaction at a specific time
MS 1a
Recognise and use expressions in decimal form
MS 1c
Use ratios, fractions and percentages
MS 1d
Make estimates of the results of simple calculations
MS 4a
Translate information between graphical and numeric form
MS 4b
Drawing and interpreting appropriate graphs from data to determine rate of reaction
MS 4c
Plot two variables from experimental or other data
MS 4d
Determine the slope and intercept of a linear graph
MS 4e
Draw and use the slope of a tangent to a curve as a measure of rate of change
Factors which affect the rates of chemical reactions
Concentrations of reactants in solution
Pressure of reacting gases
Surface area of solid reactants
Temperature
Presence of catalysts
Students should be able to recall how changing these factors affects the rate of chemical reactions
This topic offers opportunities for practical work and investigations in addition to required practical 5
Required practical 5: investigate how changes in concentration affect the rates of reactions by a method involving measuring the volume of a gas produced and a method involving a change in colour or turbidity
This should be an investigation involving developing a hypothesis
AT skills covered by this practical activity
1
3
5
6
This practical activity also provides opportunities to develop WS and MS
Collision theory
Explains how various factors affect rates of reactions. According to this theory, chemical reactions can occur only when reacting particles collide with each other and with sufficient energy
Activation energy
The minimum amount of energy that particles must have to react
Increasing the concentration of reactants in solution, the pressure of reacting gases, and the surface area of solid reactants
Increases the frequency of collisions and so increases the rate of reaction
Increasing the temperature
Increases the frequency of collisions and makes the collisions more energetic, and so increases the rate of reaction
Students should be able to predict and explain using collision theory the effects of changing conditions of concentration, pressure and temperature on the rate of a reaction
Students should be able to predict and explain the effects of changes in the size of pieces of a reacting solid in terms of surface area to volume ratio
Students should be able to use simple ideas about proportionality when using collision theory to explain the effect of a factor on the rate of a reaction
Catalysts
Change the rate of chemical reactions but are not used up during the reaction. Different reactions need different catalysts. Enzymes act as catalysts in biological systems
Catalysts increase the rate of reaction by
Providing a different pathway for the reaction that has a lower activation energy
Students should be able to identify catalysts in reactions from their effect on the rate of reaction and because they are not included in the chemical equation for the reaction
Students should be able to explain catalytic action in terms of activation energy
Students do not need to know the names of catalysts other than those specified in the subject content
An opportunity to investigate the catalytic effect of adding different metal salts to a reaction such as the decomposition of hydrogen peroxide
Reversible reactions
In some chemical reactions, the products of the reaction can react to produce the original reactants. Such reactions are called reversible reactions and are represented: A + B ⇌ C + D