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Thermodynamics
Entropy
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Created by
Juliana Zavala Rizo
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Entropy (∆S) is the measure of the
disorder
of a system
Entropy of a
molecule
is always
zero
Molecules in the
solid
phase have a
lower
entropy compared to the liquid and gas phase
As mass
increases
so does
entropy
As the number of
bonds
in the molecules increases so does
entropy
If entropy is
greater
than zero the reaction is creating
disorder
and is spontaneous
If entropy is
less
than zero the reaction is becoming more ordered
Entropy can be
positive
or
negative
Positive entropy
has
more product molecules
than reactant molecules
Negative entropy
has
more
reactant molecules than product molecules
Increase in volume =
Increased
entropy (
more
particles)
Increase in temperature =
Increased
entropy
Entropy
increases
with phases (
Solid
<
Liquid
<<
Gas
)
Entropy is calculate as follows:
S
°
r
x
n
=
S° rxn =
S
°
r
x
n
=
∑
S
°
p
r
o
d
u
c
t
s
−
∑
S
°
r
e
a
c
t
a
n
t
s
∑ S° products - ∑ S° reactants
∑
S
°
p
ro
d
u
c
t
s
−
∑
S
°
re
a
c
t
an
t
s
More motion = Greater
entropy