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1.2
Physical chem
ion transport
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Cards (19)
What is the formula for
activity
?
ai
=
γ
(mi/1mol kg-1)
What is the mean activity coefficient?
a = γ
m
what
does γ depend on?
Depends on
m
and the
electrolyte
What
is the Debye-Hückel theory?
Electrolytes
dissociate into
ions
into solution
What
is the Debye-Hückel limiting law?
logγ = -A (
Z+Z-
)I ^(
1/2
)
What
is the formula for I?
I =
1/2
sum (Z^2 *
Mi/1
)
What
is salting in?
Effect when adding
salt
to a solvent containing
organic solute increases
the solubility of that solute
What
is salting out?
Solubility
of non electrolyte in water
decreases
with the increase in concentration of a salt.
What is membrane potential?
Φ =
Φ2
-
Φ1
What
does transport of ions across biological membranes depend on?
Activity
gradient and membrane
potential
gradient
What
is the formula for activity gradient?
G
=
RTln
(a in /a out)
What is the membrane potential gradient?
G = RTLn (
ain
/
a
out
) +
ZF
+
G
What
is the Goldman equation?
RT/F Ln Sum of Pi
What is a reducing agent?
substance that
loses electrons
What is an
oxidising
agent?
an electron
acceptor
What is the difference between galvanic and electrolytic cells?
Galvanic - Ecell
>
0
Electrolytic - Ecell
<
0
What is the formula for standard cell potential?
E
cell
= E cathode -
E
anode
What is the nernest equation?
RT
/
NF lnk
What is the biological standard conditions?
25
degrees C , ph
7
, i bar and a = 1