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Organic Chemistry
Functional Groups
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Functional
groups
Group of
atoms
that is largely responsible for the chemical behavior of the
parent
molecule.
−
O
−
H
-O-H
−
O
−
H
Class:
Alcohol
General formula:
ROH
Functional group:
Hydroxyl
Group
RCHO
Class:
Aldehyde
Functional Group:
Carbonyl
group
RCOR'
Class:
Ketone
Functional group:
Carbonyl
group
RCOOH
Class:
Carboxylic Acid
Functional Group:
Carboxyl Group
ROR
'
Class:
Ether
Functional Group:
Ether
group
RCOOR
'
Class:
Ester
Functional group:
Ester
group
R
−
N
H
2
R-NH_2
R
−
N
H
2
Class: Amine
General Formula: RNR'R"
Functional group: Amino group
A)
B)
C)
3
RCONR
'R"
Class:
Amide
Functional group:
Amide
group
Alcohol
An organic compound that contains one or more hydroxyl groups
−
O
H
-OH
−
O
H
Aldehydes and Ketones
Have the carbonyl group (C=O) as their functional group
Polar in nature
A)
B)
2
Carboxylic
Acids
Have the carboxyl group -COOH
Polar
in nature
Ethers
Contains the
R-O-R'
linkage where R and R' are
hydrocarbon
groups
Extremely
flammable
Esters
General formula R’COOR where R’ can be H or a
hydrocarbon
group and R is a
hydrocarbon
Polar
Saponification
: Common reaction of
esters
(used in soap making)
Amines
Organic bases have the general formula
R3N
, where R may be H or a
hydrocarbon
Amides
A carbonyl
carbon
atom is linked by a single bond to a
nitrogen
atom and either a hydrogen or a carbon atom (RCONR'R")