Groundwater lies beneath the ground surface, filling pores in sediments and sedimentary rocks and fractures in other rock types, representing 0.6% of the hydrosphere, resupplied by slow infiltration of precipitation (recharge), generally cleaner than surface water, accessed by wells.
Porosity is the percentage of rock or sediment that consists of voids or openings, measurement of a rock’s ability to hold water, loose sand has ~30-50% porosity, compacted sandstone may have only 10-20% porosity.
Permeability is the capacity of a rock to transmit fluid through pores and fractures, interconnectedness of pore spaces, most sandstones and conglomerates are porous and permeable, granites, schists, unfractured limestones are impermeable.
The pore space of an aquifer is the spaces or voids between the solid material, the porosity of the aquifer is the volume of void space to the total volume, typically expressed as a percentage.
Porosity is highly dependent upon the arrangement, shape, and size of the material, but the diameter of the grain size does not affect porosity, since it is the ratio of open space volume to total volume.
The arrangement of various grains is called the degree of sorting and is illustrated below, well-sorted samples typically have higher porosity than poorly sorted samples, poorly sorted samples contain grains that tend to fill in the void spaces.
Contaminant concentrations in the unsaturated zone may be present in four physical states: gas, sorbed to soil materials, dissolved in water, or immiscible liquid.
Unconfined Aquifer – Has a water table, and is only partly filled with water – Rapidly recharged by precipitation infiltrating down to the saturated zone.
The transition zone thickness depends on both natural conditions such as permeability of the geological formation, tidal and recharge fluctuations and other factors such as artificial influences such as man-induced.
The driving force of seawater intrusion into the aquifer is due to excess pumpage, which lowers the freshwater table, changing the direction and magnitude of groundwater gradients.
Lack of fresh water presents a global problem of huge dimensions and a major effort is required to ensure good quality drinking water for the world population.
Seawater can contaminate a freshwater aquifer through several pathways, including lateral intrusion from the ocean, by upward intrusion from deeper, more saline zones of groundwater system, and by downward intrusion from coastal waters.
Manukan island is an ideal location for studying hydrochemical changes due to seawater intrusion due to the factors of it having been affected by seawater intrusion for many years and deteriorating due to the increase of human activities on the island.