When a metal atom reacts with a non metal atom, electrons in the outer shell of the metal atom are transferred. Metal atoms lose electrons to become positively charged ions. Non-metal atoms gain electrons to become negatively charged ions.
The electrons in the outer shell of metal atoms are delocalised and so are free to move through the whole structure. The sharing of delocalised electrons gives rise to strong metallic bonds.
As the side of a cube decreases in length by a factor of 10, its surface area to volume ratio increases by a factor of 10. This means nanoparticles have a very high surface to volume ratio, with the majority of atoms contained at the surface.